Hollow cobalt sulfide nanocapsules for electrocatalytic selective transfer hydrogenation of cinnamaldehyde with water
نویسندگان
چکیده
منابع مشابه
Electrocatalytic hydrogen evolution in acidic water with molecular cobalt tetraazamacrocycles.
A series of water-soluble molecular cobalt complexes of tetraazamacrocyclic ligands are reported for the electrocatalytic production of H(2) from pH 2.2 aqueous solutions. The comparative data reported for this family of complexes shed light on their relative efficiencies for hydrogen evolution in water. Rotating disk electrode voltammetry data are presented for each of the complexes discussed,...
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The recyclability of water-soluble ruthenium – phosphine complex catalysts was investigated in water – toluene and in water – pressurized carbon dioxide systems for selective hydrogenation of trans-cinnamaldehyde (CAL). For the first hydrogenation run, the selectivity for cinnamyl alcohol (COL) is high for both toluene and dense CO2, because of interfacial catalysis in which the reaction mainly...
متن کاملSelectivity control in Pt-catalyzed cinnamaldehyde hydrogenation
Chemoselectivity is a cornerstone of catalysis, permitting the targeted modification of specific functional groups within complex starting materials. Here we elucidate key structural and electronic factors controlling the liquid phase hydrogenation of cinnamaldehyde and related benzylic aldehydes over Pt nanoparticles. Mechanistic insight from kinetic mapping reveals cinnamaldehyde hydrogenatio...
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ژورنال
عنوان ژورنال: Cell Reports Physical Science
سال: 2021
ISSN: 2666-3864
DOI: 10.1016/j.xcrp.2021.100337